Email this article Effect of Bridging Group Nature on the Extraction Ability of Diphenylphosphorylketones toward Actinides and Lanthanides
- Authors: Safiulina A.M.1,2, Borisova N.E.3,4, Lizunov A.V.1, Golubev A.V.3, Bodrin G.V.4, Goryunov E.I.4, Goryunova I.B.4, Brel’ V.K.4, Tananaev I.G.5,6,7
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Affiliations:
- Bochvar High-Technology Research Institute of Inorganic Materials
- Mendeleev University of Chemical Technology of Russia
- Moscow State University
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Kola Scientific Center, Russian Academy of Sciences
- Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences
- Far Eastern Federal University
- Issue: Vol 68, No 11 (2023)
- Pages: 1656-1663
- Section: ФИЗИКОХИМИЯ РАСТВОРОВ
- URL: https://kld-journal.fedlab.ru/0044-457X/article/view/666157
- DOI: https://doi.org/10.31857/S0044457X23600585
- EDN: https://elibrary.ru/DJFGHV
- ID: 666157
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Abstract
Effect of structure of phosphorylketones containing flexible alkyl and conformationally rigid fragments in the linker on extraction ability toward actinides and lanthanides has been studied. It has been shown that the introduction of conformationally rigid cycloalkanediyl and alkenediyl fragments in the bridge between P=O and C=O groups in the structure of molecule decreases efficiency of extractants for both actinides and lanthanides. At the same time, the introduction of flexible alkyl groups in linker structure increases complexing and extraction ability. This dependence has been explained theoretically by modeling complexation (DFT, PBE, cc-pVDZ), monodentate coordination was observed for all studied phosphorylalkanones
About the authors
A. M. Safiulina
Bochvar High-Technology Research Institute of Inorganic Materials; Mendeleev University of Chemical Technology of Russia
Email: AMSafiulina@bochvar.ru
123098, Moscow, Russia; 125047, Moscow, Russia
N. E. Borisova
Moscow State University; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: AMSafiulina@bochvar.ru
119991, Moscow, Russia; 119334, Moscow, Russia
A. V. Lizunov
Bochvar High-Technology Research Institute of Inorganic Materials
Email: AMSafiulina@bochvar.ru
123098, Moscow, Russia
A. V. Golubev
Moscow State University
Email: AMSafiulina@bochvar.ru
119991, Moscow, Russia
G. V. Bodrin
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: AMSafiulina@bochvar.ru
119334, Moscow, Russia
E. I. Goryunov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: AMSafiulina@bochvar.ru
119334, Moscow, Russia
I. B. Goryunova
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: AMSafiulina@bochvar.ru
119334, Moscow, Russia
V. K. Brel’
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: AMSafiulina@bochvar.ru
119334, Moscow, Russia
I. G. Tananaev
Kola Scientific Center, Russian Academy of Sciences; Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences; Far Eastern Federal University
Author for correspondence.
Email: AMSafiulina@bochvar.ru
184209, Apatity, Russia; 184209, Apatity, Russia; 690090, Vladivostok, Russia
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