Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се 3 F 10  ⋅ 3Н 2 О

E. G. Il’in; Ильин Е. Г.; A. S. Parshakov; Паршаков А. С.; L. D. Iskhakova; Исхакова Л. Д.; S. Yu. Kottsov; Котцов С. Ю.; A. D. Filippova; Филиппова А. Д.; L. V. Goeva; Гоева Л. В.; N. P. Simonenko; Симоненко Н. П.; A. E. Baranchikov; Баранчиков А. Е.; V. K. Ivanov; Иванов В. К.

doi:10.31857/S0044457X23600688

Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се₃F₁₀ ⋅ 3Н₂О

Authors: Il’in E.G.¹, Parshakov A.S.¹, Iskhakova L.D.², Kottsov S.Y.¹, Filippova A.D.¹, Goeva L.V.¹, Simonenko N.P.¹, Baranchikov A.E.¹, Ivanov V.K.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Dianov Fiber Optics Research Center, Prokhorov Institute of General Physics, Russian Academy of Sciences
Issue: Vol 68, No 10 (2023)
Pages: 1348-1357
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://kld-journal.fedlab.ru/0044-457X/article/view/666162
DOI: https://doi.org/10.31857/S0044457X23600688
EDN: https://elibrary.ru/FXKZEP
ID: 666162

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Abstract

The behavior of cerium tetrafluoride hydrate was studied in water at a temperature of 80°C and under hydrothermal treatment at 100, 130, and 220°C for a day. The product of the hydrothermal treatment of CeF4·H2O at 100°C was investigated by chemical, thermogravimetric, IR spectroscopic, and X-ray powder diffraction analyses, which identified a new cerium fluoride with the composition, presumably, Ce3F10⋅3H2O or, most likely, (H3O)Ce3F10⋅2H2O. New compound crystallizes in the space group
with a unit cell parameter of 11.66 Å. Hydrothermal treatment of cerium tetrafluoride hydrate at temperatures above 130°C leads to hydrolysis and reduction of cerium(IV) fluoride compounds to form CeO2 and CeF3.

Keywords

cerium tetrafluoride, cerium trifluoride, cerium dioxide, rare earth elements

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