SINGLE-ATOM ALLOY Pd1Ag6/Al2O3 EGG-SHELL CATALYST FOR SELECTIVE ACETYLENE HYDROGENATION

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

In this work, a single-atom alloy Pd1Ag6/Al2O3 catalyst for the selective hydrogenation of acetylene was obtained with an egg-shell distribution of the active phase over the catalyst granules. The formation of an egg-shell structure was confirmed by electron probe microanalysis. It was found that metals are predominantly localized at a depth of 130–160 µm from the surface of the granules. Transmission electron microscopy and X-ray photoelectron spectroscopy have revealed the formation of a substitutional PdAg solid solution with electron density transfer from Ag to Pd. The formation of Pd1 single sites was confirmed by FTIR spectro-scopy of adsorbed CO. In the selective hydrogenation of acetylene the synthesized single-atom alloy Pd1Ag6/Al2O3 with egg-shell distribution showed high selectivity, which radically exceeds the selectivity of the palladium counterpart.

Авторлар туралы

I. Mashkovsky

Zelinsky Institute of Organic Chemistry RAS

Хат алмасуға жауапты Автор.
Email: im@ioc.ac.ru
Russian Federation, 119991, Moscow

D. Melnikov

Zelinsky Institute of Organic Chemistry RAS; Gubkin University

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow; Russian Federation, 119991, Moscow

P. Markov

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

G. Baeva

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

N. Smirnova

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

G. Bragina

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

A. Stakheev

Zelinsky Institute of Organic Chemistry RAS

Хат алмасуға жауапты Автор.
Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

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Қосымша файлдар


© И.С. Машковский, Д.П. Мельников, П.В. Марков, Г.Н. Баева, Н.С. Смирнова, Г.О. Брагина, А.Ю. Стахеев, 2023