Optimization of R2O2Se (R = La, Gd, Y) Synthesis for the Preparation of Optical Materials

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Abstract

We have perfected processes for the synthesis of lanthanum, gadolinium, and yttrium oxyselenides by heating oxides in flowing hydrogen and selenium vapor. The optimal selenidation temperature is 700°C for lanthanum, 850°C for gadolinium, and 900°C for yttrium. Subsequent annealing of the materials in flowing hydrogen at 1000°C makes it possible to remove trace levels of amorphous selenium and impurity phases containing diselenide groups.

About the authors

T. A. Pomelova

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Email: tarasen@niic.nsc.ru
Россия, 630090, Новосибирск, пр. Академика Лаврентьева, 3

M. S. Tarasenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Email: tarasen@niic.nsc.ru
Россия, 630090, Новосибирск, пр. Академика Лаврентьева, 3

I. V. Yushina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Email: tarasen@niic.nsc.ru
Россия, 630090, Новосибирск, пр. Академика Лаврентьева, 3

V. V. Malyutina-Bronskaya

Optics, Optoelectronics, and Laser Engineering State Research and Production Corporation, 220072, Minsk, Belarus

Email: tarasen@niic.nsc.ru
Беларусь, 220072, Минск, пр. Независимости, 68

V. E. Fedorov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Email: tarasen@niic.nsc.ru
Россия, 630090, Новосибирск, пр. Академика Лаврентьева, 3

N. G. Naumov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

Author for correspondence.
Email: tarasen@niic.nsc.ru
Россия, 630090, Новосибирск, пр. Академика Лаврентьева, 3

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Copyright (c) 2023 Т.А. Помелова, М.С. Тарасенко, И.В. Юшина, В.В. Малютина-Бронская, В.Е. Федоров, Н.Г. Наумов