Features of the Synthesis of Few-Layer Phosphorene Structures During Plasma Electrochemical Cleavage of Black Phosphorus

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A comparative study of the emission spectra of cathode electrolysis plasma during plasma electrochemical cleavage of black phosphorus and graphite under maximally identical experimental conditions has been carried out. A significantly lower concentration of active intermediates (OH radicals and O atoms) in the electrolysis plasma during the cleavafe of black phosphorus was found compared with a graphite electrode. It is assumed that this effect is due to a significantly higher rate of interaction of these intermediates with synthesized phosphorene structures than with graphene-like particles. This is confirmed by the detection of a much higher oxygen content in the products of black phosphorus cleavage than in synthesized carbon nanoparticles.

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V. Kochergin

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences

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Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

R. Manzhos

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

N. Komarova

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

A. Kotkin

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

A. Krivenko

Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

I. Krushinskaya

Branch of N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

A. Pelmenyov

Branch of N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kochergin@icp.ac.ru
俄罗斯联邦, Chernogolovka

参考

  1. Tiouitchi G., El Manjli F., Mounkachi O. et al. // Jordan J. Phys. 2020. V. 13. P. 149.
  2. Zhang Y., Jiang Q., Lang P. et al. // J. Alloys Compd. 2021. V. 850. P. 156580.
  3. Goswami A., Gawande M.B. // Front. Chem. Sci. Eng. 2019. V. 13. P. 296.
  4. Shu C., Zhou J., Jia Z. et al. // Chem. Eur. J. 2022, V. 28. P. e202200857.
  5. Srivastava R., Nouseen S., Chattopadhyay J. et al. // Energy Technol. 2021. V. 9. P. 2000741.
  6. Valappi M.O., Alwarappan S., Pillai V.K. // Nanoscale. 2022. V. 14. P. 1037.
  7. Xue X-X., Shen S., Jiang X. et al. // J. Phys. Chem. Lett. 2019. V. 10. P. 3440.
  8. Wang Y., He M., Ma S., Yang C. et al. // J. Phys. Chem. Lett. 2020. V. 11. P. 2708.
  9. Kochergin V.K., Manzhos R.A., Komarova N.S. et al. // High Energ. Chem. 2022. V. 56. P. 487.
  10. Krivenko A.G., Manzhos R.A., Kochergin V.K. et al. // High Energ. Chem. 2019. V. 53. P. 254.
  11. Kramida A., Ralchenko Yu., Reader J., NIST ASD Team. NIST Atomic Spectra Database (ver. 5.9), https://physics.nist.gov/asd
  12. Hubner K.P., Herzberg G. Molecular Spectra and Molecular Structure, V. IV: Constants of Diatomic Molecules. New York: Van Northland, 1979. parts 1, 2.
  13. Очкин В.Н. Спектроскопия низкотемпературной плазмы. М.: Физматлит, 2006.
  14. Бобровников С.М., Горлов Е.В., Жарков В.И., Сафьянов А.Д. // Оптика атмосферы и океана. 2022. Т. 35. № 8. С. 613.
  15. Belkin P.N., Kusmanov S.A. // Surf. Eng. Appl. Electrochem. 2021. V. 57. №. 1. P. 19.
  16. Dittrich K., Fuchs H. // J. Anal. Atom. Spectrom. 1990. V. 5. P. 39.
  17. Ambrosi A., Bonanni A., Pumera M. // Nanoscale. 2011. V. 3. № 5. P. 2256.

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2. Fig. 1. The scheme of the experimental setup for the synthesis of MFS

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3. Fig. 2. Overview spectra of cathode electrolysis plasma recorded during the splitting of CF – 1 (black line) and graphite – 2 (gray line). The inset shows the IR part of the spectrum at an enlarged scale

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4. Fig. 3. SEM images of phosphorene (a) and graphene (b) structures

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