Control of Technological Parameters of Detonation Spraying for Obtaining Coatings Based on Titanium Dioxide with Specified Wetting Properties

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Abstract

The study of the water-repellent properties of the surface of a metal-ceramic coating for protective purposes based on dioxide titanium is carried out. It is shown that the water-repellent properties of the coating surface can be effectively changed by varying the technological parameters of spraying. During the production of coatings, such technological parameters as the distance from the substrate to the barrel of the detonation gun and the speed of its passage are changed. A pattern is identified that connects the technological parameters of detonation coating spraying and the contact angle of wetting. It is established that the dependence of the contact angle on the spraying distance obeys a parabolic law under certain conditions. The parameters of phenomenological equation that adequately describes the observed parabolic dependence are calculated. The optimal values of the technological parameters of detonation spraying necessary to achieve maximum hydrophobicity of the produced coatings have been determined.

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V. V. Sirota

Белгородский государственный технологический университет имени В. Г. Шухова

Author for correspondence.
Email: savotchenkose@mail.ru
Russian Federation, Белгород

S. E. Savotchenko

Белгородский государственный технологический университет имени В. Г. Шухова; Российский государственный геологоразведочный университет имени Серго Орджоникидзе

Email: savotchenkose@mail.ru
Russian Federation, Белгород; Москва

V. V. Strokova

Белгородский государственный технологический университет имени В. Г. Шухова

Email: savotchenkose@mail.ru
Russian Federation, Белгород

D. S. Podgorony

Белгородский государственный технологический университет имени В. Г. Шухова

Email: savotchenkose@mail.ru
Russian Federation, Белгород

S. V. Zaytsev

Белгородский государственный технологический университет имени В. Г. Шухова

Email: savotchenkose@mail.ru
Russian Federation, Белгород

A. S. Churikov

Белгородский государственный технологический университет имени В. Г. Шухова

Email: savotchenkose@mail.ru
Russian Federation, Белгород

M. G. Kovaleva

Белгородский государственный национальный исследовательский университет

Email: savotchenkose@mail.ru
Russian Federation, Белгород

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Supplementary files

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2. Fig. 1. Optical image of the substrate surface (height map)

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3. Fig. 2. Optical image of the coating surfaces obtained at d = 40 mm, s = 400 mm/min (a) and s = 2000 mm/min (b)

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4. Fig. 3. Dependence of roughness Ra (μm) on the detonation gun passage speed s (mm/min)

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5. Fig. 4. Dependence of the edge angle θ (°) on the sputtering distance d (mm)

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6. Fig. 5. Distribution of edge angle values θ (°) at different detonation gun passage velocities s (mm/min)

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7. Fig. 6. Relationship between edge angle θ (°) and roughness Ra (µm)

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8. Fig. 7. Schematic representation of gas flow distribution in the process of detonation spraying: 1 - nozzle of the detonation gun; 2 - zone of exit from the nozzle; 3 - zones of elevated temperatures; 4 - core of the detonation jet; 5 - turbulence zone; 6 - zone of mixing with atmospheric gases

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9. Fig. 8. Samples of coating spots obtained by detonation spraying of titanium powder at different distances from the nozzle (mm): 20 (a), 40 (b), 60 (c), 80 (d), 100 (e), 130 (f), 160 (g), 200 (h)

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10. Fig. 9. Dependence of mixing zone spot diameter (1) and flux core spot diameter (2) on sputtering distance (markers - experimental data, solid lines - approximation by parabolic equation, dashed line - approximation by logarithmic equation)

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