Crystal and Molecular Structure of Binuclear Technetium Carbonyl Chloride Complexes: [99TcCl(CO)3(C5H8O2)]2 (C5H8O2 = Acetylacetone) and [99TcCl(CO)4]2

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

The crystal and molecular structures of the complex [99TcCl(CO)3(C5H8O2)]2 (C5H8O2 = Hacac = acetylacetone) formed in the course of prolonged standing of a [99Tc(acac)(CO)4] solution in ССl4/CDCl3 and of its analog containing no organic ligand, [99TcCl(CO)4]2, were determined. Both complexes contain a [Tc2(μ-Cl)2] four-membered ring. The remaining sites in the coordination sphere of the Tc atom are occupied by carbonyl ligands, and in the case of [99TcCl(CO)3(Hacac)]2, also by the neutral acetylacetone molecule. The Hacac molecules in the binuclear complex are in the cis position to the Cl atoms in the octahedral surrounding of the Тс atoms and in the trans position to each other relative to the [Tc2(μ-Cl)2] ring. A comparative analysis of the geometries of the complexes and their known analogs was performed.

Texto integral

Acesso é fechado

Sobre autores

G. Sidorenko

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Autor responsável pela correspondência
Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

A. Miroslavov

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7/9, St. Petersburg, 199034

V. Gurzhiy

St. Petersburg State University

Email: gevasid@mail.ru
Rússia, Universitetskaya nab. 7/9, St. Petersburg, 199034

A. Kochergina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7/9, St. Petersburg, 199034

A. Sakhonenkova

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

M. Tyupina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozyorsk, Chelyabinsk oblast, 456783

L. Chistyi

Research Institute of Hygiene, Professional Pathology, and Human Ecology, Federal Medical-Biological Agency

Email: gevasid@mail.ru
Rússia, Zavodskaya ul. 6/2, korp. 93, Kuzmolovskii, Vsevolozhsk raion, Leningrad oblast, 188663

E. Pechertseva

Khlopin Radium Institute

Email: gevasid@mail.ru
Rússia, 2-i Murinskii pr. 28, St. Petersburg, 194021

Bibliografia

  1. Борисова И.В., Мирославов А.Е., Сидоренко Г.В., Суглобов Д.Н., Щербакова Л.Л. // Радиохимия. 1991. Т. 33. № 4. С. 28–32.
  2. Сидоренко Г.В., Григорьев М.С., Гуржий В.В., Кривовичев С.В., Мирославов А.Е., Суглобов Д.Н. // Радиохимия. 2010. Т. 52. № 2. С. 126–131; Sidorenko G.V., Grigor’ev M.S., Gurzhiy V.V., Krivovichev S.V., Miroslavov A.E., Suglobov D.N. // Radiochemistry. 2010. Vol. 52. N 2. P. 145–151. https://doi.org/10.1134/S1066362210020050
  3. Sagnou M., Benaki D., Triantis C., Tsotakos T., Psycharis V., Raptopoulou C.P., Pirmettis I., Papadopoulos M., Pelecanou M. // Inorg. Chem. 2011. Vol. 50. N 4. P. 1295–1303. https://doi.org/10.1021/ic102228u
  4. Triantis C., Tsotakos T., Tsoukalas C., Sagnou M., Raptopoulou C., Terzis A., Psycharis V., Pelecanou M., Pirmettis I., Papadopoulos M. // Inorg. Chem. 2013. Vol. 52. N 22. P. 12995–13003. https://doi.org/10.1021/ic401503b
  5. Benny P.D., Fugate G.A., Ganguly T., Twamley B., Bučar D.-K., MacGillivray L.R. // Inorg. Chim. Acta. 2011. Vol. 365. N 1. P. 356–362. https://doi.org/10.1016/j.ica.2010.09.050
  6. Sagnou M., Tsoukalas C., Triantis C., Raptopoulou C.P., Terzis A., Pirmettis I., Pelecanou M., Papadopoulos M. // Inorg. Chim. Acta. 2010. Vol. 363. N 8. P. 1649–1653. https://doi.org/10.1016/j.ica.2010.01.004
  7. Miroslavov A.E., Lumpov A.A., Sidorenko G.V., Levitskaya E.M., Gorshkov N.I., Suglobov D.N., Alberto R., Braband H., Gurzhiy V.V., Krivovichev S.V., Tananaev I.G. // J. Organomet. Chem. 2008. Vol. 693. N 1. P. 4–10. https://doi.org/10.1016/j.jorganchem.2007.09.032
  8. Акопов Г.А., Криницын А.П., Царенко А.Ф. // Радиохимия. 1987. Т. 29. № 5. С. 589–593.
  9. Мирославов А.Е., Сидоренко Г.В., Борисова И.В., Легин Е.К., Лычев А.А., Суглобов Д.Н. // Радиохимия. 1990. Т. 32. № 6. С. 14–21.
  10. CrysAlisPro. Rigaku Oxford Diffraction. Version 1.171.42.102a. 2023.
  11. Sheldrick G.M. // Acta Crystallogr., Sect. A. 2015. Vol. 71. P. 3–8. https://doi.org/10.1107/S2053273314026370
  12. Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. Vol. 71. P. 3–8. https://doi.org/10.1107/S2053229614024218
  13. Dolomanov O.V., Bourhis L.J., Gildea R.J., Howard J.A.K., Puschmann H. // J. Appl. Crystallogr. 2009. Vol. 42. N 2. P. 339–341.
  14. Hileman J.C., Huggins D.K., Kaesz H.D. // Inorg. Chem. 1962. Vol. 1. N 4. P. 933–938. https://doi.org/10.1021/ic50004a048
  15. Григорьев М.С., Мирославов А.Е., Сидоренко Г.В., Суглобов Д.Н. // Радиохимия. 1997. Т. 39. № 3. С. 207–209; Grigor’ev M.S., Miroslavov A.E., Sidorenko G.V., Suglobov D.N. // Radiochemistry. 1997. Vol. 39. N 3. P. 205–207.
  16. Vega A., Calvo V., Manzur J., Spodine E., Saillard J.-Y. // Inorg. Chem. 2002. Vol. 41. N 21. P. 5382–5387. https://doi.org/10.1021/ic020234e
  17. Zeng H., Ju J., Hua R. // Tetrahedron Lett. 2011. Vol. 52. N 30. P. 3926–3928. https://doi.org/10.1016/j.tetlet.2011.05.093
  18. Dahl L.F., Wei C.-H. // Acta Crystallogr. 1963. Vol. 16. N 7. P. 611–616. https://doi.org/10.1107/S0365110X6300164X
  19. Darst K.P., Lenhert P.G., Lukehart C.M., Warfield L.T. // J. Organomet. Chem. 1980. Vol. 195. N 3. P. 317–324. https://doi.org/10.1016/S0022-328X(00)93314-X
  20. Clegg W., Morton S. // Acta Crystallogr., Sect. B. 1978. Vol. 34. N 5. P. 1707–1709. https://doi.org/10.1107/S0567740878006421
  21. Haghiri A., Lerner H.-W., Bolte M. // Acta Crystallogr., Sect. E. 2006. Vol. 62. N 3. P. i72–i73. https://doi.org/10.1107/S1600536806005885
  22. Yan Z., Yuan X., Zhao Y., Zhu C., Xie J. // Angew. Chem. Int. Ed. 2018. Vol. 57. N 39. P. 12906–12910. https://doi.org/10.1002/anie.201807851
  23. Wang D., Dong J., Fan W., Yuan X., Han J., Xie J. // Angew. Chem. Int. Ed. 2020. Vol. 59. N 22. P. 8430–8434. https://doi.org/10.1002/anie.201916305
  24. Murray B.S., Prior T.J. CCDC 2089065: Experimental Crystal Structure Determination, 2021. https://doi.org/10.5517/CCDC.CSD.CC283V6G
  25. Davies J.A., El-Ghanam M., Pinkerton A.A. // Acta Crystallogr., Sect. C. 1991. Vol. 47. N 7. P. 1356–1358. https://doi.org/10.1107/S010827019100015X
  26. Сидоренко Г.В., Гуржий В.В., Мирославов А.Е., Сизова О.В., Кривовичев С.В., Лумпов А.А., Суглобов Д.Н. // Радиохимия. 2009. T. 51. № 3. C. 207–212; Sidorenko G.V., Gurzhii V.V., Miroslavov A.E., Sizova O.V., Krivovichev S.V., Lumpov A.A., Suglobov D.N. // Radiochemistry. 2009. Vol. 51. N 3. P. 237–243. https://doi.org/10.1134/S1066362209030047
  27. Григорьев М.С., Мирославов А.Е., Сидоренко Г.В., Суглобов Д.Н. // Радиохимия. 1997. Т. 39. № 3. С. 204–206; Grigor’ev M.S., Miroslavov A.E., Sidorenko G.V., Suglobov D.N. // Radiochemistry. 1997. Vol. 39. N 3. P. 202–204.
  28. Батурин Н.А., Григорьев М.С., Крючков С.В., Мирославов А.Е., Сидоренко Г.В., Суглобов Д.Н. // Радиохимия. 1994. T. 36. № 3. C. 199–201.
  29. Борисова И.В., Мирославов А.Е., Сидоренко Г.В., Суглобов Д.Н. // Радиохимия. 1991. Т. 33. № 3. С. 1–8.
  30. Wong A.C.C., Wilkinson G., Hussain B., Motevalli M., Hursthouse M.B. // Polyhedron. 1988. Vol. 7. N 15. P. 1363–1370. https://doi.org/10.1016/S0277-5387(00)80386-1
  31. Calderazzo F., Mavani I.P., Vitali D., Bernal I., Korp J.D., Atwood J.L. // J. Organomet. Chem. 1978. Vol. 160. N 1. P. 207–222. https://doi.org/10.1016/S0022-328X(00)91214-2
  32. Carballo R., Garcia-Martinez E., Pereiras-Gabian G., Vazquez-Lopez E.M. // Z. Naturforsch. B. 2003. Vol. 58. P. 1021–1023.
  33. Mukiza J., Gerber T.I.A., Hosten E.C., Betz R. // Z. Kristallogr.—New Cryst. Struct. 2014. Vol. 229. N 4. P. 355–356. https://doi.org/10.1515/ncrs-2014-0184
  34. Forshaw A.P., Bontchev R.P., Smith J.M. // Inorg. Chem. 2007. Vol. 46. N 10. P. 3792–3794. https://doi.org/10.1021/ic070187w
  35. Zdanovich V.I., Lobanova I.A., Petrovskii P.V., Batsanov A.S., Struchkov Yu.T., Kolobova N.E. // Russ. Chem. Bull. 1987. Vol. 36. P. 1500–1503. https://doi.org/10.1007/BF01557534
  36. Van Niekerk X., Gerber T.I.A., Hosten E.C. // Polyhedron. 2021. Vol. 203. ID 115171. https://doi.org/10.1016/j.poly.2021.115171
  37. Flörke U. // Acta Crystallogr., Sect. C. 1999. Vol. 55. IUC 9900119. https://doi.org/10.1107/S0108270199098777
  38. Adams R.D., Belinski J.A., Chen L. // Organometallics. 1992. Vol. 11. N 12. P. 4104–4108. https://doi.org/10.1021/om00060a029
  39. Bezuidenhout D.I., Lotz S., Landman M., Liles D.C. // Inorg. Chem. 2011. Vol. 50. N 4. P. 1521–1533. https://doi.org/10.1021/ic101784w
  40. Fredette M.C., Lock C.J.L. // Can. J. Chem. 1973. Vol. 51. N 7. P. 1116–1122. https://doi.org/10.1139/v73-165

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2. Fig. 1. Molecular structure of the complex [99TcCl(CO)4]2.

Baixar (228KB)
Metadados
3. Fig. 2. Packing of [TcCl(CO)4]2 molecules in the crystal lattice, projection on the ab (a) and as (b) planes. The contours of the unit cell are shown.

Baixar (945KB)
Metadados
4. Fig. 3. Molecular structure of the complex [99TcCl(CO)3(Hacac)]2.

Baixar (91KB)
Metadados
5. Fig. 4. Packing of [TcCl(CO)3(Hacac)]2 molecules in the crystal lattice, projection on the bc (a) and ab (b) plane. The contours of the unit cell are shown.

Baixar (981KB)
Metadados

Declaração de direitos autorais © Russian Academy of Sciences, 2024