Гидрофобные эвтектические растворители на основе спиртов и камфоры в экстракции Fe(III) из солянокислых растворов

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Abstract

Предложены новые гидрофобные эвтектические растворители на основе линалоола, гераниола и камфоры в качестве экстрагентов для ионов Fe(III) из солянокислых растворов. Изучены температурные зависимости ключевых физических свойств предложенных эвтектических растворителей. Исследована экстракция ионов Fe(III) из водных растворов в зависимости от условий проведения процесса: кислотность среды, соотношение компонентов в эвтектическом растворителе, концентрация высаливателя и объемное соотношение фаз. При экстракции хлорида железа гидрофобными эвтектическими растворителями линалоол/камфора и гераниол/камфора в органической фазе образуются соединения состава (ROH2)+[FeCl4]–. Добавление камфоры улучшает экстракционные свойства спиртов, при этом гераниол является наиболее эффективным экстрагентом, нежели линалоол. Реэкстракция ионов Fe(III) из органической фазы осуществляется дистиллированной водой без введения дополнительных реагентов.

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About the authors

А. В. Кожевникова

Институт общей и неорганической химии им. Н.С. Курнакова РАН

Email: yz@igic.ras.ru
Russian Federation, Москва, 119991

И. В. Зиновьева

Институт общей и неорганической химии им. Н.С. Курнакова РАН

Email: yz@igic.ras.ru
Russian Federation, Москва, 119991

Ю. А. Заходяева

Институт общей и неорганической химии им. Н.С. Курнакова РАН

Author for correspondence.
Email: yz@igic.ras.ru
Russian Federation, Москва, 119991

А. А. Вошкин

Институт общей и неорганической химии им. Н.С. Курнакова РАН

Email: yz@igic.ras.ru
Russian Federation, Москва, 119991

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Supplementary files

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1. JATS XML
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2. Fig. 1. Structural formulas: a) linalool, b) geraniol, c) camphor.

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3. Fig. 2. IR spectra of camphor (1), HES linalool/camphor (2) and geraniol/camphor (3).

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4. Fig. 3. IR spectra of geraniol (1), linalool (2), HES geraniol/camphor 1/1 (3) and HES linalool/camphor 1/1 (4).

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5. Fig. 4. Dependence of refractive index (a), density (b) and viscosity (c) on temperature for HES: linalool/camphor 1/1 (1) and geraniol/camphor 1/1 (2).

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6. Fig. 5. Dependence of the degree of extraction of Fe(III) ions on the contact time of the phases; [HCl] = 3 and 4 mol/l for HES geraniol/camphor 1/1 and HES linalool/camphor 1/1, respectively.

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7. Fig. 6. Dependence of the degree of extraction of Fe(III) ions on the concentration of HCl in the aqueous phase.

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8. Fig. 7. Dependence of the degree of extraction of Fe(III) ions on the alcohol content in HESs; [HCl] = 3 and 5 mol/l for HES geraniol/camphor 1/1 and HES linalool/camphor 1/1, respectively.

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9. Fig. 8. Dependence of the degree of extraction of Fe(III) ions on the concentration of LiCl in the aqueous phase; [HCl] = 2 and 3 mol/l for HES geraniol/camphor 1/1 and HES linalool/camphor 1/1, respectively.

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10. Fig. 9. Dependence of the degree of extraction of Fe(III) ions on the ratio of aqueous and organic phases; [HCl] = 3 and 5 mol/l for HES geraniol/camphor 1/1 and HES linalool/camphor 1/1, respectively.

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