Corrosion Properties of TiNi Medical Alloy with Bioinert Coatings

V. I. Urban; Урбан В. И.; V. V. Rubanik; Рубаник В. В.; V. V. Rubanik; Рубаник мл. В. В.; D. A. Bagrets; Багрец Д. А.; V. D. Dorodeiko; Дородейко В. Г.; D. E. L. Vieira; Vieira D. E. L.; A. N. Salak; Salak A. N.

doi:10.31857/S0044185623700523

Corrosion Properties of TiNi Medical Alloy with Bioinert Coatings

Authors: Urban V.I.¹, Rubanik V.V.¹, Rubanik V.V.¹, Bagrets D.A.¹, Dorodeiko V.D.², Vieira D.E.³, Salak A.N.³
Affiliations:
1. Institute of Technical Acoustics, Belarus National Academy of Sciences
2. ZAO Simurg Medical Enterprise
3. Department of Materials and Ceramic Engineering, CICECO-Aveiro Institute of Materials, University of Aveiro
Issue: Vol 59, No 4 (2023)
Pages: 444-450
Section: ФИЗИКО-ХИМИЧЕСКИЕ ПРОБЛЕМЫ ЗАЩИТЫ МАТЕРИАЛОВ
URL: https://kld-journal.fedlab.ru/0044-1856/article/view/663939
DOI: https://doi.org/10.31857/S0044185623700523
EDN: https://elibrary.ru/WSCZSV
ID: 663939

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

A comparative analysis of the barrier properties and corrosion resistance of bioinert coatings of tantalum, zirconium nitride, stainless steel of the 12X18H10T grade, as well as diamond-like coating (DLC) deposited on the surface of the medical alloy Ti–50.8 at % Ni (TiNi) has been performed. All the coatings are characterized by high barrier properties with respect to the yield of nickel in the biological medium for a long time, whereas, in the case of uncoated TiNi, the concentration of nickel in the test solution increases rapidly and exceeds the permissible amount of migration after 60 days of exposure. Electroplating TiNi–bioinert-coating pairs demonstrate a corrosive behavior determined by the nature of the coating material. The most resistant to galvanic corrosion is the TiNi –Ta pair, for which no signs of corrosion processes were detected on any of the elements of the pair after exposure in a model solution for 24 h. The pairs TiNi–12X18H10T and TiNi–DLC have shown the worst corrosion resistance among the studied pairs: extensive corrosion areas were observed on one of the elements of the pairs.

Keywords

titanium nickelide, ZrN coating, Ta coating, 12X18H10T stainless-steel coating, diamond-like coating, galvanic pair, stationary potential, anode current

References

Гюнтер В.Э. Никелид титана. Медицинский материал нового поколения. Томск: Изд-во МИЦ, 2006. 296 с.
O’Brien W.J. Dental materials and their selection. Quintessence Publ. Co. Inc. 2002. 418 p.
Kasprzak K.S., Bialkowski K. // J. Inorg. Biochem. 2000. V. 79. P. 231–236.
Takamura K., Hayashi K., Ishinishi N., Yamada T., Sugioka Y. // J. Biomed. Mat. Res. 1994. V. 28. P. 583–589.
Калита В.И. // Физика и химия обработки материалов. 2000. № 5. С. 28–45.
Wang G., Zreiqat H. // Functional Coatings or Films for Hard-Tissue Applications: review, Materials. 2010. № 3. P. 3994–4050.
Углов В.В., Злоцкий С.В., Солодухин И.А., Малашевич А.А. // Журн. Белорусского государственного университета. Физика. 2019. № 2. С. 105–111.
Ramoul C., Beliardouh N.E., Bahi R., Nouveau C., Djahoudi A., Walock M.J. // Tribology – Materials, Surfaces & Interfaces. 2019. V. 13(1). P. 12–19.
Kim W.G., Kim D.Y., Choe H.C. // J. Korean institute of surface engineering. 2008. V. 41. Issue 4. P. 163–168.
Мейснер Л.Л., Лотков А.И., Гудимова Е.Ю., Остапенко М.Е. // Вестник ТГУ. 2013. Т. 18. № 4. С. 1827–1828.
Park C., Kim S., Kim H.E., Jang T.S. // Surf. Coat. Technol. 2016. V. 305. P. 139–145.
Казбанов В.В., Баталов М.С., Вишневский А.А. // Проблемы здоровья и экологии. 2015. № 2(44). С. 16–23.
Ma W.J., Ruys A.J., Mason R.S., Martin P.J., Bendavid A., Liu Z., Ionescu M., Zreiqat H. // Biomaterials. 2007. V. 28. P. 1620–1628.
Bahrets D.A., Rubanik V.V., Vieira D.E.L., Salak A.N. // Russian J. Electrochemistry. 2020. V. 56. № 12. P. 989–996.
ГОСТ 31577-2012. Протезы зубные металлические с защитными покрытиям, Москва: Стандартинформ, 2013. 11 с.
Niinomi M. // JOM. 1999. V. 51. № 6. P. 32–34.
Hu T., Chu C., Xin Y., Wu S., Yeung K.W.K., Chu P.K. // J. Materials Research. 2010. V. 25. № 2. P. 350–358.
Ünal İ., Zor S., Atapek H. // Materials Science. 2012. V. 47. № 6. P. 830–837.
Об утверждении санитарных норм и правил “Требования к изделиям медицинского назначения и медицинской технике”: постановление Совета Министров Респ. Беларусь, 16 дек. 2013 г. № 128 // ЭТАЛОН. Законодательство Республики Беларусь / Нац. Центр правовой информ. Респ. Беларусь. Минск, 2021.