Thermochemical Study of Bismuth Cobalt Dysprosium Oxide: The Enthalpy of Formation and Lattice Enthalpy

N. I. Matskevich; Мацкевич Н. И.; A. N. Semerikova; Семерикова А. Н.; N. V. Gel’fond; Гельфонд Н. В.; V. P. Zaitsev; Зайцев В. П.; M. Yu. Matskevich; Мацкевич М. Ю.; O. I. Anufrieva; Ануфриева О. И.; A. A. Fedorov; Федоров А. А.

doi:10.31857/S0044457X23601402

Thermochemical Study of Bismuth Cobalt Dysprosium Oxide: The Enthalpy of Formation and Lattice Enthalpy

Авторлар: Matskevich N.I.¹, Semerikova A.N.¹, Gel’fond N.V.¹, Zaitsev V.P.¹^,2, Matskevich M.Y.¹, Anufrieva O.I.¹, Fedorov A.A.¹
Мекемелер:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2. Siberian State University of Water Transport
Шығарылым: Том 68, № 12 (2023)
Беттер: 1786-1791
Бөлім: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://kld-journal.fedlab.ru/0044-457X/article/view/666073
DOI: https://doi.org/10.31857/S0044457X23601402
EDN: https://elibrary.ru/BWNIYL
ID: 666073

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Қосымша файлдар
Статистика

Аннотация

Bismuth cobalt dysprosium oxide of composition Bi12.5Dy1.5CoO22.325 has been prepared by solid-state reactions. The compound has a cubic structure (space group Fm
m) with the unit cell parameter a = 0.55279(5) nm. The solution enthalpy and standard enthalpy of formation of Bi12.5Dy1.5CoO22.325 have been measured by solution calorimetry: ΔsolH0 = −1017.0 ± 7.5 kJ/mol, and ΔfH0 = −5338.8 ± 19.9 kJ/mol. The lattice enthalpy has been calculated using the Born–Haber cycle: ΔlatH0 = −99020 kJ/mol. The lattice enthalpy increases in magnitude as the lanthanide radius decreases in the neodymium–dysprosium–holmium series.

Негізгі сөздер

bismuth oxide, cobalt oxide, dysprosium oxide, enthalpy of formation, lattice enthalpy

Әдебиет тізімі

Crumpton T.E., Mosselmans J.F.W., Creaves C. // J. Mater. Chem. 2005. V. 15. P. 164. https://doi.org/10.1039/b412108m
Yue Ya., Dziegielewska A., Zhang M. et al. // Chem. Mater. 2023. V. 35. P. 189. https://doi.org/10.1021/acs.chemmater.2c03001
Gagarin P.G., Guskov A.V., Gavrichev K.S. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 2183. https://doi.org/10.1134/S0036023622602070
Lomanova N.A. // Russ. J. Inorg. Chem. 2022. V. 67. P. 741. https://doi.org/10.1134/S0036023622060146
Pandey P., Dixit P., Chauhan V. et al. // J. Alloys Compd. 2023. V. 952. P. 169911. https://doi.org/10.1016/j.jallcom.2023.169911
Kaimieva O.S., Sabirova I.E., Buyanova E.S. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1348. https://doi.org/10.1134/S0036023622090054
Jankovsky O., Sedmidubsky D., Leitner J. et al. // Thermochim. Acta. 2014. V. 582. P. 40. https://doi.org/10.1016/j.tca.2014.02.022
Dmitriev A.V., Vladimirova E.V., Kellerman D.G. et al. // J. Alloys Compd. 2019. V. 777. P. 586. https://doi.org/10.1016/j.jallcom.2018.10.387
Elovikov D.P., Tomkovich M.V., Levin A.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 850. https://doi.org/10.1134/S0036023622060067
Steblevskaya N.I., Belobeletskaya M.V., Medkov M.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1228. https://doi.org/10.1134/S0036023622080265
Milewska K., Maciejewski M., Lapinski M. et al. // J. Non-Cryst. Solids. 2023. V. 605. P. 122169. https://doi.org/10.1016/j.jnoncrysol.2023.122169
Balci M., Saatci B., Turk H. et al. // Mater. Today Comm. 2022. V. 33. P. 104542. https://doi.org/10.1016/j.mtcomm.2022.104542
Crumpton T.E., Greaves C. // J. Mater. Chem. 2004. V. 14. P. 2433. https://doi.org/10.1039/b405770h
Lv P., Huang F. // RSC Advances. 2019. V. 9. P. 8650. https://doi.org/10.1039/c8ra09565e
Capoen E., Steil C., Boivin J.C. et al. // Solid State Ionics. 2006. V. 177. P. 483. https://doi.org/10.1016/j.ssi.2005.12.015
Emel’yanova Yu.V., Mikhailovskaya Z.A., Buyanova E.S. et al. // Russ. J. Appl. Chem. 2017. V. 90. P. 354. https://doi.org/10.1134/S1070427217030053
Krok F., Abrahams I., Holdynski M. et al. // Solid State Ionics. 2008. V. 179. P. 975. https://doi.org/10.1016/j.ssi.2008.02.015
Hervoches C.H., Greaves C. // Solid State Ionics. 2014. V. 254. P. 1. https://doi.org/10.1016/j.ssi.2013.10.032
Matskevich N.I., Wolf Th., Pischur D. et al. // J. Therm. Anal. Calorim. 2016. V. 124. P. 1745. https://doi.org/10.1007/s10973-016-5316-y
Kekade S.S., Gaikwad P.V., Raut S.A. et al. // ACS Omega. 2018. V. 3. P. 5853. https://doi.org/10.1021/acsomega.8b00564
Punn R., Feteira A.M., Sinclair D.C. et al. // J. Am. Chem. Soc. 2006. V. 128. P. 15386. https://doi.org/10.1021/ja065961d
Matskevich N.I., Wolf Th., Greaves C. et al. // J. Chem. Thermodyn. 2015. V. 91. P. 234. https://doi.org/10.1016/j.jct.2015.07.036
Minenkov Yu.F., Matskevich N.I., Stenin Yu.G. et al. // Thermochim. Acta. 1996. V. 278. P. 1. https://doi.org/10.1016/0040-6031(95)02801-3
Matskevich N.I., McCallum R.W. // Thermochim. Acta. 1999. V. 342. P. 41. https://doi.org/10.1016/s0040-6031(99)00314-7
Matskevich N.I., Krabbes G., Berasteguie P. // Thermochim. Acta. 2003. V. 397. P. 97. https://doi.org/10.1016/S0040-6031(02)00330-1
Kilday M.V. // J. Res. Nat. Bur. Stand. 1980. V. 85. P. 467.
Gunther C., Pfestorf R., Rother M. et al. // J. Therm. Anal. Calorim. 1988. V. 33. P. 359.
Termicheskie konstanty veshchestv (Thermal Constants of Substances) / Ed. Glushko V.P. M.: VINITI, 1965–1982. V. 1–10.
Matskevich N.I., Semerikova A.N., Samoshkin D.A. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 1825. https://doi.org/10.1134/S0036023622600988
Shannon R.D. // Acta Crystallogr., Sect. A. 1976. V. 32. P. 751. https://doi.org/10.1107/S0567739476001551