Estimated hansen solubility parameters of low-dimensional vanadium, niobium and tantalum dichalcogenides

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

Low-dimensional flakes of transitional metal dichalcogenides TaX2 (X = S, Se, Te), VSe2 and NbSe2 were acquired using liquid-phase exfoliation process. Hansen solubility parameters of those dispersions were estimated by measuring extinction in a number of various liquid environments. Amount of low-dimensional particles of dichalcogenides in a sample increases with decrease of Hansen distance between dichalcogenide and exfoliation medium. We propose a method to qualitatively estimate the impact exfoliation medium has on the size of forming particles and demonstrate how decrease of the absolute value of δpolar and δhydrogen in examined systems leads to decrease in size of forming flakes.

About the authors

К. S. Nikonov

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

Т. К. Menshikova

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

М. N. Brekhovskikh

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: nikonovk.s@yandex.ru
Russian Federation, Moscow

References

  1. Coleman J.N., Lotya M., O’Neill A. et al. // Science. 2011. V. 331. № 6017. Р. 568. https://doi.org/10.1126/science.1194975
  2. Hildebrand H.J. Solubility of Non-electrolytes. N.Y.: Reinhold Publ. Corp., 1936. 203 p.
  3. Süß S., Sobisch T., Peukert W. et al. // Adv. Powder Technol. 2018. V. 29. № 7. P. 1550. https://doi.org/10.1016/j.apt.2018.03.018
  4. Venkatram Sh., Kim Ch., Chandrasekaran A., Ramprasad R. // J. Chem. Inf. Model. 2019. V. 59. № 10. P. 4188. https://doi.org/10.1021/acs.jcim.9b00656
  5. Садовников С.И. // Журн. неорган. химии. 2023. V. 68. № 3. P. 411. https://doi.org/10.31857/S0044457X22601559
  6. Mathieu D. // ACS Omega. 2018. V. 3. № 12. P. 17049. https://doi.org/10.1021/acsomega.8b02601
  7. Gilliam M.S., Yousaf A., Guo Y., et al. // Langmuir. 2021. V. 37. № 3. Р. 1194. https://doi.org/10.1021/acs.langmuir.0c03138
  8. Cunningham G., Lotya M., Cucinotta C.S. et al. // ACS Nano. 2012. V. 6. № 4. P. 3468. https://doi.org/10.1021/nn300503e
  9. Kumar S., Pratap S., Joshi N. et al. // Micro and Nanostructures. 2023. V. 181. P. 207627. https://doi.org/10.1016/j.micrna.2023.207627
  10. Eaglesham D.J., Withers R.L., Bird D.M. // J. Phys. C: Solid State Phys. 1986. V. 19. № 3. P. 359. https://doi.org/10.1088/0022–3719/19/3/006
  11. Xi X., Zhao L., Wang Z. et al. // Nature Nanotech. 2015. V. 10. P. 765. https://doi.org/10.1038/nnano.2015.143
  12. Zhou L., Sun Ch., Li X. et al. // Nano Express. 2020. V. 15. P. 20. https://doi.org/10.1186/s11671-020-3250-1
  13. Mahajan M., Kallatt S., Dandu M. et al. // Commun. Phys. 2019. V. 2. Р. 88. https://doi.org/10.1038/s42005-019-0190-0
  14. Wu J., Peng J., Yu Zh. et al. // J. Am. Chem. Soc. 2018. V. 140. № 1. Р. 493. https://doi.org/10.1021/jacs.7b11915
  15. Yang W., Gan L., Li H. et al. // Inorg. Chem. Front. 2016. V. 3. Р. 433. https://doi.org/10.1039/C5QI00251F
  16. Jia Y., Liao Y., Cai H. // Nanomaterials. 2022. V. 12. P. 2075. https://doi.org/10.3390/nano12122075
  17. Wang J., Guo C., Guo W. et al. // Chinese Phys. B. 2019. V. 28. № 4. Р. 046802. https://doi.org/10.1088/1674-1056/28/4/046802
  18. Li H., Tan Y., Liu P. et al. // Adv. Mater. 2016. V. 28. № 40. P. 8945. https://doi.org/10.1002/adma.201602502
  19. Wang F., Mao J. // Mater. Horiz. 2023. V. 10. № 5. P. 1780. https://doi.org/10.1039/D3MH00072A
  20. Никонов К.С., Ильясов А.С., Бреховских М.Н. // Журн. неорган. химии. 2020. Т. 65. № 9. С. 1222. https://doi.org/10.1134/S0036023620090120
  21. Yang L., Zhao R., Wu D. et al. // Sensors. 2021. V. 21. № 1. P. 239. https://doi.org/10.3390/s21010239
  22. Hansen Ch.M. Hansen Solubility Parameters: A User’s Handbook. Boca Raton, London, NY: CRC Press, 2007. 544 p.
  23. Segets D., Gradl J., Taylor R.К. et al. // ACS Nano. 2009. V. 3. № 7. Р. 1703. https://doi.org/10.1021/nn900223b

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2024 Russian Academy of Sciences