The Rate of Absorption by the Styrene Epoxide–P-Toluene Sulfonic
Acid Double System Depending on the Structure of the Aliphatic Tail
of the Alcohol Solvent

V. M. Solyanikova; Соляников В. М.; L. V. Petrov; Петров Л. В.

doi:10.31857/S0207401X23120129

The Rate of Absorption by the Styrene Epoxide–P-Toluene Sulfonic Acid Double System Depending on the Structure of the Aliphatic Tail of the Alcohol Solvent

Autores: Solyanikova V.M.¹, Petrov L.V.¹
Afiliações:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Edição: Volume 42, Nº 12 (2023)
Páginas: 12-17
Seção: Kinetics and mechanism of chemical reactions, catalysis
URL: https://kld-journal.fedlab.ru/0207-401X/article/view/675006
DOI: https://doi.org/10.31857/S0207401X23120129
EDN: https://elibrary.ru/JTCNJB
ID: 675006

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Somente assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

Oxygen oxidation of the styrene epoxide (SE)–p-toluene sulfonic acid (TSA) double system (DS)
in solutions of three primary alcohols, 1-octanol (OCT), n-butanol (BUT), and ethanol (ET), is studied. The
corresponding concentration expressions of oxidation rates are as follows: VOCT = k [SE]0 [TSA]1, VBUT = k
[SE]0 [TSA]0.63, and VET = k [SE]0 [TSA]0.7 at [SE] [TSA]. The proximity of the oxidation activation energies
in three alcohols contrasts with the difference in the oxidation rates: the oxidation rate in ET is three
times the rate in n-butanol and thirty times the oxidation rate in 1-octanol.

Palavras-chave

Oxidation by molecular oxygen, catalysis, styrene epoxide, p-toluene sulfonic acid, 1-octanol, nbutanol, ethanol

Sobre autores

V. Solyanikova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: plv@icp.ac.ru
Chernogolovka, Russia

L. Petrov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: plv@icp.ac.ru
Chernogolovka, Russia

Bibliografia

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