Features of Cl  K -edge XANES spectra of metal transition complexes {MCl 6 }  n –  (M = Rh, Pd, Re, Os, Ir, Pt)

A. D. Fedorenko; Федоренко А. Д.; I. P. Asanov; Асанов И. П.; T. I. Asanova; Асанова Т. И.; D. B. Vasilchenko; Васильченко Д. Б.; A. D. Nikolenko; Николенко А. Д.; P. A. Piminov; Пиминов П. А.; K. Yu. Karyukina; Карюкина К. Ю.

doi:10.31857/S0367676522701253

Features of Cl K-edge XANES spectra of metal transition complexes {MCl₆}^n– (M = Rh, Pd, Re, Os, Ir, Pt)

作者: Fedorenko A.D.¹, Asanov I.P.¹, Asanova T.I.¹, Vasilchenko D.B.¹, Nikolenko A.D.²^,3^,4, Piminov P.A.³^,4, Karyukina K.Y.³^,4
隶属关系:
1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
2. Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”
3. Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences
4. Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences
期: 卷 87, 编号 5 (2023)
页面: 738-746
栏目: Articles
URL: https://kld-journal.fedlab.ru/0367-6765/article/view/654415
DOI: https://doi.org/10.31857/S0367676522701253
EDN: https://elibrary.ru/ABHSZL
ID: 654415

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详细

Cl K-edges of a set of chlorides of 4d- and 5d-transition metals {MCl₆}^n– (M = Rh, Pd, Re, Os, Ir, Pt) were obtained using the “Cosmos” station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical methods made it possible to determine the magnitude of the spin-orbit interaction (SOC) depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, as well as stretched and compressed complexes.

作者简介

A. Fedorenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

I. Asanov

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

T. Asanova

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

D. Vasilchenko

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk

A. Nikolenko

Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”; Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

P. Piminov

Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences; Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis
of Siberian Branch of the Russian Academy of Sciences

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

K. Karyukina

Email: fedorenko@niic.nsc.ru
Russia, 630090, Novosibirsk; Russian, 630559, Koltsovo

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