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1-Hydro-1,10-phenanthrolinium perchlorate and 1,10-Dihydro-1,10-phenanthrolinium Perchlorate in the Reaction of Electrocatalytic Production of Molecular Hydrogen
- Authors: Yudina A.D.1, Boykova T.V.1, Ganz O.Y.1, Klimaeva L.A.1, Ulyakina Y.V.1, Burmistrova A.A.1, Karpunina T.O.1, Okina E.V.1
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Affiliations:
- National Research Ogarev Mordovia State University
- Issue: Vol 60, No 10 (2024)
- Pages: 1017-1024
- Section: Articles
- URL: https://kld-journal.fedlab.ru/0514-7492/article/view/682482
- DOI: https://doi.org/10.31857/S0514749224100026
- EDN: https://elibrary.ru/QNBTES
- ID: 682482
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Abstract
Using the cyclic voltammetry method, the electrochemical and electrocatalytic properties for hydrogen evolution reaction of the 1-hydro-1,10-phenanthrolinium perchlorate (I) and 1,10-dihydro-1,10-phenanthrolinium perchlorate (II) in the presence of CF3COOH were studied. The presence of hydrogen atoms at nitrogen in heterocyclic compounds has a significant effect on the electrochemical properties and the efficiency of the electrocatalytic process. The transition from 1-hydro-1,10-phenanthrolinium perchlorate (I) to 1,10-dihydro-1,10-phenanthrolinium perchlorate (II) leads to an increase in the efficiency of the process (higher TOF and TON values), despite identical mechanisms. The DFT method was used to study the mechanisms of the processes taking place and identify key intermediates.
About the authors
A. D. Yudina
National Research Ogarev Mordovia State University
Author for correspondence.
Email: dolganov_sasha@mail.ru
ORCID iD: 0000-0002-1269-1609
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
T. V. Boykova
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Bolshevistskaya st. 68, Saransk 430005
O. Yu. Ganz
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
L. A. Klimaeva
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
ORCID iD: 0000-0003-3050-4720
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
Yu. V. Ulyakina
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
A. A. Burmistrova
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
T. O. Karpunina
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
E. V. Okina
National Research Ogarev Mordovia State University
Email: dolganov_sasha@mail.ru
Russian Federation, Bolshevistskaya st. 68, Saransk 430005
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