Poly(1-trimethylsilyl-1-propyne) of a cis-Rich Configuration — a Membrane Material for the Separation of Butane/Methane Mixtures as Natural Gas Components

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Acesso é pago ou somente para assinantes

Resumo

In this work, for the first time, we studied the permeability of individual lower hydrocarbons and in a C1/C4 mixture for films based on PTMSP of a new cis-enriched configurational composition (the content of cis-units in the samples was 80 and 90%). The methane permeability of freshly prepared cis-regular PTMSP films (90% of cis-units) exposed to air for a month is higher than the corresponding values of PTMSP films with 80% cis-units. The X-ray diffraction data indicate a looser packing of the cis-regular PTMSP. The introduction of the antioxidant Irganox 1076 into PTMSP films leads to a decrease in the initial level of the methane flux. At the same time, the permeability of films with the addition of Irganox 1076 over time (within 1 month) decreases much more slowly compared to films without the addition of an antioxidant. The permeability of individual lower hydrocarbons through PTMSP films without and with the addition of Irganox 1076 increases in the order С1 < C2 < C3 < C4. The value of the separation factor in the n-butane/methane mixture reaches 33, which is almost 7 times higher than the selectivity for individual components. The high level of n‑butane permeability of cis-enriched PTMSP is maintained for at least a month of films storage in air.

Sobre autores

V. Makrushin

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
Russia, 119991, Moscow

A. Kossov

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
Russia, 119991, Moscow

I. Levin

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
Russia, 119991, Moscow

D. Bezgin

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
Russia, 119991, Moscow

D. Syrtsova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: matson@ips.ac.ru
Russia, 119991, Moscow

S. Matson

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Autor responsável pela correspondência
Email: matson@ips.ac.ru
Russia, 119991, Moscow

Bibliografia

  1. Neubauer K., Dragomirova R., Stohr M., Mothes R., Lubenau U., Paschek D., Wohlrab S. // J. Membr. Sci. 2014. V. 453. P. 100.
  2. Pinnau I., Toy L.G. // J. Membr. Sci. 1996. V. 116. P. 199.
  3. Toy L.G., Nagai K., Freeman B.D., Pinnau I., He Z., Masuda T., Teraguchi M., Yampolskii Yu. // Macromolecules. 2000. V. 33. 7. P. 2516.
  4. Nagai K., Toy L.G., Freeman B.D., Teraguchi M., Masuda T., Pinnau I. // J. Polym. Sci. Part B: Polym. Phys. 2000. V. 38. P. 1474.
  5. Morisato A., Pinnau I. // J. Membr. Sci. 1996. V. 121. P. 243.
  6. Pinnau I., He Z., Morisato A. // J. Membr. Sci. 2004. V. 241. P. 363.
  7. Thomas S., Pinnau I., Do N., Guiver M.D. // J. Membr. Sci. 2009. V. 338. P. 1.
  8. Yampolskii Yu., Durgaryan S., Nametkin N. // Vysokomol. Soed., Ser. B. 1979. V. 21. P. 616.
  9. Nagai K., Toy L.G., Freeman B.D., Teraguchi M., Kwak G., Masuda T., Pinnau I. // J. Polym. Sci. Part B: Polym. Phys. 2002. V. 40. P. 2228.
  10. Yave W., Peinemann K., Shishatskiy S., Khotimskiy V., Chirkova M, Matson S., Litvinova E., Lecerf N. // Macromolecules. 2007. V. 40. P. 8991.
  11. Hu Y., Shiotsuki M., Sanda F., Freeman B.D., Masuda T. // Macromolecules. 2008. V. 41. P. 8525.
  12. Bermeshev M.V., Syromolotov A.V., Starannikova L.E., Gringolts M.L., Lakhtin V.G., Yampolskii Y.P., Finkelshtein E.S. // Macromolecules. 2013. V. 46. P. 8973.
  13. Gringolts M., Bermeshev M., Yampolskii Yu., Starannikova L., Shantarovich V., Finkelshtein E. // Macromolecules. 2010. V. 43. P. 7165.
  14. Borisov I.L., Grushevenko E.A., Anokhina T.S. Bakhtin D.S., Levin I.S., Bondarenko G.N. Volkov V.V., Volkov A.V. // Materials Today Chemistry. 2021. V. 22. P. 100598.
  15. Logemann M., Alders M., Pyankova V., Krakau D., Wessling M. // J. Membr. Sci. 2020. V. 615. P. 118 430.
  16. Masuda T., Isobe E., Higashimura T., Takada K. // J. Am. Chem. Soc. 1983. V. 105/ P. 7473.
  17. Ichiraku Y., Stern S.A., Nakagawa T. // J. Membr. Sci. 1987. V. 34. P. 5.
  18. Srinivasan R., Auvil S.R., Burban P.M. // J. Membr. Sci. 1994. V. 86. P. 67.
  19. Nagai K., Nakagawa T. // J. Membr. Sci. 1995. V. 105. P. 261.
  20. Schultz J., Peinemann K.V. // J. Membr. Sci. 1996. V. 110. P. 37.
  21. Morisato A., Shen H.C., Sankar S.S., Freeman B.D, Pinnau I., Casillas C.G. // J. Polym. Sci. Part B: Polym. Phys. 1996. V. 34. P. 2209.
  22. Pinnau I., Casillas G.C., Morisato A., Freeman B.D. // J. Polym. Sci. Part B: Polym. Phys. 1998. V. 35. P. 1483.
  23. Nagai K., Freeman B.D., Hill A.J. // J. Polym. Sci. Part B: Polym. Phys. 2000. V. 38. P. 1222.
  24. Merkel T.C., Bondar V., Nagai K., Freeman B.D. // J. Polym. Sci. Part B: Polym. Phys. 1999. V. 38. P. 273.
  25. Nagai K., Masuda T., Nakagawa T., Freeman B.D., Pinnau I. // Prog. Polym. Sci. 2001. V. 26. P. 721.
  26. Raharjo R.D., Freeman B.D., Sanders E.S. // J. Membr. Sci. 2007. V. 292. P. 45.
  27. Freeman B. D., Pinnau I. Polymer membranes for gas and vapor separation. Washington, DC, USA: American Chemical Society, 1999. V. 733.
  28. Zhmakin V., Shalygin M., Khotimskiy V., Matson S., Teplyakov V. // Sep. Pur. Tech. 2019. V. 212. P. 877.
  29. Khotimsky V.S., Tchirkova M.V., Litvinova E.G., Rebrov A.I., Bondarenko G.N. // J. Polym. Sci. Part A: Polym. Chem. 2003. V. 41. P. 2133.
  30. Khotimsky V.S., Matson S.M., Litvinova E.G., Bondarenko G.N., Rebrov A.I. // Polym. Sci., Ser. A. 2003. V. 45. P. 740.
  31. Hill A.J., Pas S.J., Bastow T.J., Burgar M.I., Nagai K., Toy L.G., Freeman B.D. // J. Membr. Sci. 2004. V. 243. P. 37.
  32. Матсон С.М., Коссов А.А., Макрушин В.П., Левин И.С., Жиляева Н.А., Литвинова Е.Г., Хотимский В.С. // Высокомолек. Cоед. Сер. C. 2019. Т. 61. С. 50.
  33. Матсон С.М., Макрушин В.П., Левин И.С., Литвинова Е.Г., Хотимский В.С. // Мембраны и мембранные технологии. 2020. Т. 10. С. 409.
  34. Литвинова Е.Г., Мелехов В.М., Петрушанская Н.В., Рощева Г.В., Федотов В.Б., Фельдблюм В.Ш., Хотимский В.С. Пат. 1823457 Российская Федерация. 1993.
  35. Pinnau I.C., Casillas G.A. Morisato A., Freeman B.D. // J. Polym. Sci, Part B: Polym. Phys. 1996. V. 34. P. 2613.
  36. Plate N.A., Bokarev A.K., Kaliuzhnyi N.E., Litvinova E.G., Khotimskii V.S., Volkov V.V., Yampolskii Yu.P. // J. Membr. Sci. 1991. V. 60. P. 13.
  37. Yampolskii Yu.P. // Polym. Rev. 2017. V. 57. P. 200.
  38. База Данных “Газоразделительные параметры стеклообразных полимеров”. Информрегистр РФ.1998. № 3585.
  39. Yampolskii Yu.P., Korikov A.P., Shantarovich V.P., Nagai K., Freeman B.D., Masuda T., Teraguchi M., Kwak G. // Macromolecules. 2001. V. 34. P. 1788.
  40. Thomas S., Pinnau I, Du N., Guiver M.D. // J. Membr. Sci. 2009. V. 333. P. 125.
  41. Markova S.Yu., Pelzer M., Shalygin M.G., Vad T., Gries T., Teplyakov V.V. // Sep. Pur. Tech. 2022. V. 278. P. 11953.
  42. Grinevich Yu.V., Starannikova L.E., Yampolskii Yu.P., Gringolts M.L., Finkelshtein E.Sh. // J. Membr. Sci. 2011. V. 378. P. 250.
  43. Gringolts M.L., Bermeshev M.G., Yampolskii Yu.P., Starannikova L.E., Shantarovich V.P., Finkelshtein E.Sh. // Macromolecules. 2010. V. 43. P. 7165.
  44. Yave W., Car A., Peinemann K.-V., Shaikh M.Q., Rätzke K., Faupe F. // J. Membr. Sci. 2009 V. 339. P. 177.
  45. Pinnau I., Morisato A., He Z. // Macromolecules. 2004. V. 37. P. 2823.
  46. Borman V.D., Teplyakov V.V., Tronin V.N., Tronin I.V., Troyan V.I. // J. Exp. Theor. Phys. 2000. V. 90. P. 950.
  47. Zhmakin V.V., Teplyakov V.V. // Sep. Pur. Tech. 2017. V. 186. P. 145.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar
2.

Baixar (23KB)
Metadados
3.

Baixar (38KB)
Metadados
4.

Baixar (92KB)
Metadados
5.

Baixar (70KB)
Metadados
6.

Baixar (44KB)
Metadados
7.

Baixar (54KB)
Metadados

Declaração de direitos autorais © В.П. Макрушин, А.А. Коссов, И.С. Левин, Д.А. Безгин, Д.А. Сырцова, С.М. Матсон, 2023