


Vol 88, No 6 (2024)
Articles
К 100-летию со дня рождения профессора Уно Хермановича Копвиллема



Quantum Optics and Coherent Spectroscopy
Multiparameter quantum metrology with bright solitons
Abstract
We consider the problem of quantum metrology with simultaneous measurement of several phase parameters in the framework of current tendencies of development of alternative navigation. The fundamental limits of linear and nonlinear metrology are studied. The effect of losses on the accuracy of quantum metrology for several parameters is revealed. A realistic scenario for preparing three-mode NooN states using atomic bright solitons is proposed.



Simulation of atomic motion by random shift of transition frequencies in the method of coupled dipoles
Abstract
We study the influence of atomic motion on the optical properties of atomic ensembles cooled in special laser traps. We analyze the possibility to simulate the continuous displacement of atoms within the framework of motionless coupled dipoles method, in which slow motion is modeled, firstly, by averaging over their random spatial distribution, and, secondly, by introducing a random shift of their frequencies, simulating Doppler effects. A direct comparison of the results obtained for moving atoms with the model ones revealed a very limited range of applicability of the latter.



Optical dynamics of a supercrystal of V-type quantum emitters: effects of the electronic states' dephasing
Abstract
A theoretical study of the optical response of a two-dimensional supercrystal (monolayer) of quantum emitters with a doublet in the excited state to the action of a continuous external field has been carried out, considering the dephasing of the electronic states of the system. The secondary field acting on the V-emitter from other V-emitters of the system forms their nonlinearity and provides internal positive feedback, which leads to bistability, periodic and aperiodic auto-oscillations and including chaotic behavior. In the presence of dephasing, the multistability of the optical response is preserved. Phase relaxation leads to a change in the scenario of the system dynamics from chaos to periodic oscillations of the field amplitude, i. e., to a “chaos — limit cycle” bifurcation, a decrease in the reflectivity of the monolayer in linear and nonlinear modes.



Atom-photon cluster in nonlinear and quantum optics
Abstract
We described the constructed models of radiative quantum systems analogous of multiphoton and Raman resonances of classical field quanta on an atomic system with the participation of resonator mode quanta. A distinctive feature of the models is the possibility to describe an atomic ensemble and quanta using either the generators of polynomial algebra or the two-mode Jordan-Schwinger representation of the su(2) algebra, that could point to atomic-photon and/or photon clusters. The algebras are arising that are mathematically insoluble, in contrast to the Heisenberg — Weyl algebra, which makes it possible to implement and observe fundamental effects of coherent nonlinear optics, such as photon echo, optical nutation, and superradiance in ensembles of the described clusters.






Spatial coherence of exciton-polaritoniс Bose‒Einstein condensates
Abstract
Dynamics of exciton-polariton Bose‒Einstein condensate in an optical microcavity is considered. A novel version of stochastic Gross‒Pitaevsky equation for description of condensate evolution under non-Markovian interaction with environment is proposed. Using the proposed version, analysis of condensate dynamics for various temperatures is carried out. The phase transition from a homogeneous to fragmented condensate state near temperature of 15 K is found. This phase transition is accompanied by drop of condensate density and decrease of correlation length. It is found that correlation length oscillates with time for the temperature of 10 K. The results obtained indicate the necessity to take into account non-Markovianity of condensate interaction with the excitonic reservoir.



NaYF4: Yb, Er based nanosensors testing for temperature measurements in biological media
Abstract
NaYF4: Yb, Er particles were synthesized by hydrothermal method in the form of rods of 1.4 µm × 70 nm average size. Their surface was modified with L-cysteine, which provided hydrophilic properties. It was shown that the modified particles exhibit upconversion luminescence in the visible spectral range upon 980 nm laser excitation. Their temperature calibration in physiological solution was carried out. The possibility of remote temperature measurement in the biologically significant range of temperature (293—323 K) with an average sensitivity of 43 × 10—4 K—1 and an accuracy of ±1.0 K was shown. A demonstration experiment was performed on the living nervous system of the grape snail Helix lucorum. The nanosensors have been successfully used for bioimaging and remote low-invasive temperature measurement with a spatial resolution of 10 µm.



Three-Airy beams and their autofocusing plane
Abstract
The position of the autofocusing plane of three-Airy beams is studied theoretically and experimentally depending on the shift parameter. It is shown that for different values of this parameter, the three-Airy beam may or may not have an autofocusing plane. If the beam has an autofocusing plane, then with increasing absolute value of the shift parameter, the autofocusing plane monotonically moves away from the initial plane.



Klyshko method for analog photodetectors and absolute measurement of photon numbers
Abstract
A modification of the Klyshko method for absolute calibration of analog photodetectors is considered. It is shown that the photocurrent distribution of an analog detector can be approximated by convolution of the Poisson distribution of the number of photoelectrons with a function describing single photopulses, while the number of photons incident on the detector can be determined from the statistical properties of biphoton radiation. The ratio of the number of photoelectrons to the number of photons gives the efficiency of an analog photodetector, which can be used for measuring the intensity of radiation incident on the detector in units of photon numbers.



Spatial selectivity of the four-wave radiation converter considering the rotation of the polydisperse nanosuspension layer
Abstract
The influence of the layer incline of the polydisperse nanosuspension on the spatial structure of the object wave is analyzed. Due to the layer incline the fine structure appears in the modulus of its spatial spectrum around the dip. The dependences of the dip half-width on the standard deviation in the particle size distribution and the incline angle are obtained. The optimal angles at which the dip half-width takes on the minimal value are determined.



On the optical autowaves in non-equilibrium media
Abstract
A brief overview of the author’s theoretical research on localized optical autowaves is presented. One-dimensional autowaves accompanied by the formation of localized quasi-monochromatic and unipolar autosolitons at their fronts are considered. The lifetimes of such objects are on the order of the relaxation times of the populations of quantum levels of non-equilibrium media. The characteristic durations of autosolitons exceed the phase relaxation times.



Deactivation of triplet states of the metalloporphyrins by molecular oxygen
Abstract
The values of the phosphorescence decay time of the metalloporphyrins upon selective excitation into the absorption bands and the atmospheric concentration of molecular oxygen in solution has been recorded at 293 K. It was demonstrated that the decay time of triplet states depends on the polarity of the solvents, as well as on the wavelength of the excitation.



Dependence of the values of fluorescence quantum yields for porphyrins and phthalocyanines from the effects of reabsorption
Abstract
The values of fluorescence quantum yield upon using by the procedures of relative and of absolute quantum yields were measured for a set of porphyrins and phthalocyanines with different activities of bands in the absorption spectrum. The correlations between of the values quantum yields and optical densities at the absorption bands of the samples has been estimated that provides an opportunity to estimate the nature of the internal filter effects.



Generation of Terahertz Radiation by Atomic Systems at Different Ratios of Frequencies between Components of Interacting Two-Color Laser Fields
Abstract
The generation of terahertz radiation by atomic systems interacting with femtosecond two-color laser fields (ω1 + ω2) formed by the fundamental harmonic of a laser source (ω1) and radiation with frequencies varying over a wide range (ω2) is studied. It is shown that the efficiency of the generation of terahertz radiation grows when ratio of frequencies between components of the two-color field is close but not equal to 2, and difference |ω2 – 2ω1| corresponds to the terahertz range. A numerical experiment is performed using laser sources with wavelengths from the near- to far-infrared range.



Luminescence and Laser Physics
Lasing from molecular nitrogen ions in laser plasma
Abstract
We presented the results of study of lasing from molecular nitrogen ions in laser plasma produced by femtosecond radiation pulse. It is shown that the maximum intensities at the wavelengths of 391.4 and 427.8 nm are observed at nitrogen pressure of 30 and 500 mbar respectively. The radiation divergence is tens mrad and is close to geometric. When the focal length of lens changes from 15 to 40 cm the pulse duration at wavelength of 391.4 nm varies from 1.83 to 3.5 ps.



Fluorescent research of antibiotic phototransformation in aqueous solution
Abstract
We presented a spectral-luminescent study of the sulfaguanidine phototransformation in aqueous solution under the action of ultraviolet lamp OUVb-04 (180—275 nm), KrCl (222 nm), XeBr (282 nm) and XeCl (308 nm) excilamps. An analysis of the conversion of sulfaguanidine in water shows that, under the action of XeBr excilamp radiation, the efficiency of sulfaguanidine phototransformation in water is comparable to the decrease upon excitation of OUVb-04, but higher than upon irradiation with KrCl or XeCl excilamps. The maximum loss for sulfaguanidine is 99 % without the introduction of additional oxidizing agents. After irradiation, several photoproducts of various nature were recorded.



Photophysical properties of phosphors based on 3-(1,3-benzothiazol-2-yl)-4-hydroxybenzenesulfonic acid
Abstract
Water-soluble organic phosphors based on 3-(1,3-benzothiazol-2-yl)-4-hydroxybenzene sulphonic acid were first studied experimentally and by density functional theory. The phosphors have differences in chemical structure. For one of them there is a large Stokes shift that results from intramolecular proton transfer in the excited state.



Ground station efficiency for quantum communications
Abstract
We investigated the possibility of practical implementation of a quantum communication link for encryption key distribution between a Micius satellite and a mobile ground optical station. Thanks to theoretical estimation numerical values of the main parameters of such a communication link are obtained: total loss, key generation rate and secret key length, as well as quantum bit error rate.



Optimized frequency recovery of the satellite quantum signal
Abstract
We developed the frequency recovery method of laser pulses necessary for synchronizing quantum states transmitted from a satellite and registered at a ground station. Experimental modeling of a quantum key distribution session between a satellite and a ground station is also considered. The data obtained during the experiment were used to test the method of recovering the repetition frequency.



Improving length estimation of the secret key in satellite-to-ground quantum channel
Abstract
We study and optimize the length of the secret sequence depending on the intervals of splitting the communication session between the satellite and the ground station during the quantum key distribution. Due to dynamically changing channel parameters, the proposed technique allows for significant increases in the final key rate and length.



Luminescence systems in diamond at 489 nm
Abstract
In the photoluminescence spectra of natural type Ia diamond crystals, a zero-phonon line with a position of 488.9 nm (2.53 eV) is observed. The excitation spectrum of the system is mirror to the emission spectrum. The 488.9 nm line has phonon repetitions corresponding to an energy of 0.073 eV. A change in temperature from 77 to 313 K shifts the position of the system by 1.01 nm toward the red region, and the decrease in intensity and broadening of full width at half maximum is non-linear. The characteristics of the electron-phonon interaction and distribution in the bulk of the crystals of a defect with a zero-phonon line of 488.9 nm are like the characteristics of defects of a nitrogen-vacancy nature.



Effect of temperature on photoluminescence of CdSe/ZnS quantum dots in biopolymer composite with erythrosine B
Abstract
The temperature sensitivity of photoluminescence of synthesized composites based on differently charged biopolymers with colloidal CdSe/ZnS quantum dots and erythrosin B dye was studied. Due to the combined action of the mechanisms of temperature quenching and resonant energy transfer from quantum dots to the dye, the dynamic range of the analytical signal of the quantum dot photoluminescence intensity increases, which can be used to create dynamic temperature sensors.



Photoluminescence with quasi-white spectrum in LiF-UO2 crystals with color centers
Abstract
We study of spectral characteristics of LiF-UO2 crystals with radiation induced color centers and their stability under action of emission of blue light emitting diode. The luminescence band with bandwidth 500—750 nm was observed upon excitation by blue light emitting diode emission. This indicates the possibility of using LiF crystals, containing uranium and radiation induced color centers (F2, F3+), as a phosphor, that possesses high stability due to special radiation treatment, for white light sources.


